The starring role in "The Devil Wears Prada," the copious gossip page mentions, and the transformation into one of Valentino's intimates have all added to Anne Hathaway's style chops. Completing her fashion insider status is the announcement that she's been named an ambassador for the French cosmetics behemoth Lancôme. Just what the actress' role will entail has yet to be announced, but her duties will begin in September and continue for an undisclosed period of time. As Odile Roujol, president of Lancôme International, put it, "Anne Hathaway is a radiant young woman who perfectly embodies modern femininity. We know she will portray all the passion and excitement of our new fragrance."

CHANEL

Chanel is one of today’s best known and highly sought-after fashion brands, and has been practically since it was founded by Coco (Gabrielle) Chanel in 1909. The luxury brand stands out in just about every category—couture, ready-to-wear, accessories, jewelry, shoes, and fragrances. What began as a no-nonsense approach to fashion, designed to let women be comfortable while looking dignified, has been translated into classic, tailored style, especially in ready-to-wear, where the traditional tweed Chanel suit with a nipped-at-the-waist cardigan jacket remains one of the most popular—and most copied—fashion staples. The iconic, quilted leather Chanel bag is perpetually popular—and one of the most knocked-off accessories on Canal Street. Evening gowns tend to have an understated sex appeal and a bit of whimsy, and appear in luxurious fabrics with lots of embellishments.